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Unlocking the mysteries of Mars with LIBS technology

A fascinating geological study on the planet Mars has been using LIBS technology to make geochemical observations since 2012. We spoke to one of the scientists behind the project working in collaboration with NASA.

It is not often that we think of analytical technology outside the confines of an industrial setting or streamlined laboratory on our own planet. But in the case of Laser Induced Breakdown Spectroscopy (LIBS) known from the FOSS Micral™ analyzer, we are talking about a method that has been tried and tested on Mars since 2012.

 

We spoke to scientist, PhD Jens Frydenvang from the University of Copenhagen, who is using LIBS to study the geology of Mars in collaboration with NASA. Jens Frydenvang has a background in physics with a PhD in analytical chemistry focusing on LIBS.

 

He is involved in two of the most ambitious LIBS projects that exist today, taking place on Mars. One is the so-called Chemcam instrument, on board the NASA Curiosity rover that landed on Mars in 2012, the other is the Supercam instrument on board the NASA Perseverance rover that landed on Mars three years ago. 

 

The core technology inside both the Chemcam and Supercam is LIBS. The newer Supercam has been upgraded with a few more capabilities, but the technology remains the same. Both instruments have been developed in a collaboration between Los Alamos National Laboratory, in the US where LIBS was originally developed, and the French space agency CNES.

 

“I have the honor and privilege to be part of both of those instrument teams and be part of especially the calibration efforts. Understanding how we can go from the spectral information into getting the elemental composition of the rocks that we're looking at. And obviously using the geochemical data we collect to learn everything we can about the evolution of Mars,” explains Jens Frydenvang.

Jens Frydenvang explains Laser Induced Breakdown Spectroscopy

The LIBS concept defined in the 1980s requires a lot of energy to be deposited into a sample within a short period of time.

 

This is provided by a laser pulse typically lasting a few nanoseconds. The energy is deposited into the sample so quickly that a small explosion is created on the surface. This creates a weakly ionized plasma that initially emits light due to a recombination in the plasma, and eventually emits a very distinct light, that depends on what elements are in the sample. If you measure the spectrum of that light, you can identify which elements are present in the sample.

 

As the laser breaks everything apart, the elements are all that is left behind. Optics lead the laser to the sample and collect the light from the plasma, leading it to a spectrometer. That is the basics of LIBS. Depending on the kind of set-up you want, there can be all kinds of complexities such as how you want to shoot at the sample, how many pulses, and the timing in terms of when you shoot the laser and collect the light. 

 

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Geochemical observations on Mars

 

With the LIBS instrument in place the rover can measure the Martian surface within a circumference of up to about six meters. This is where the project can really benefit from the key strengths of the LIBS technology.

 

“We can get a good LIBS measurement on rocks and soil on the Martian surface. And we can do it without driving there, simply by shooting the laser from wherever the rover ends up. It's a quick observation, at least compared to any other geochemical observation we could make. An observation typically lasts around 15 minutes, and then we move on to the next target or drive on, whatever we’re up for on that particular day on Mars.”

 

The ability to shoot the laser and make analytical observations from a distance, means that it is possible to get a high volume of LIBS measurements. “That allows us to really track how the geochemical evolution varies as we as we drive across the Martian surface,” says Jens Frydenvang. 

 

“Our ability to perform a lot of observations means that ChemCam and SuperCam can be used as a scout to decide if we need to drive up to a specific outcrop and utilize our arm. We can drill into the sample and get much more detailed observations, look at the mineralogy and so on if the Chemcam LIBS instrument measurements tell us that this is truly interesting,” he adds.

Another part of the work involves continuous tracking. “We have the power, the resources, and the range to find relevant rocks to investigate and see, did anything change compared to where we were the last time. So, we have a fantastic sort of tracking of how the geochemistry has evolved as we climb up through the geological layers of a mountain on Mars.”

In terms of power, the LIBS instrument doesn't need that much, which is also an advantage.

 

Why LIBS?

 

The question arises, why LIBS? Is there another method available that could provide the same measurements? According to Jens Frydenvang the short answer is no. There are other technologies available such as X-ray fluorescence (XRF), but it requires longer analysis time or that you get very close to the sample. 

“We do have a version of X-ray fluorescence on both rovers that also provides geochemical observations. On Curiosity it is a particle induced fluorescence instrument called APXS, and on the Perseverance rover we have a micro-XRF instrument called PIXL. For both, the time it requires to get an observation is typically much greater than a single LIBS observation, and it also requires that the arm can be deployed on the target,” he explains. “Compared to X-ray fluorescence, the LIBS instrument is faster and much more flexible,” he adds. 

“In addition to that, we have the benefit that because an integral part of LIBS is that we create those explosions on the surface, it means that we quite effectively blow away dust which otherwise covers all parts of the Martian surface. So, due to the inherent concept of LIBS, we actually have a unique way of getting to the underneath rocks without being affected by the ubiquitous surficial dust.” 

Getting a clean sample surface is otherwise a pretty big issue in the case of X-ray fluorescence. On the Curiosity rover, good APXS observations typically require the use of a brush to remove dust, and on the Perseverance rover, PIXL observations are often preceded by abrading the rock with the rover drill in order to get a fresh surface. “So, there are multiple benefits where LIBS really has become a very powerful tool for planetary exploration,” concludes Jens Frydenvang.


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